Download e-book for kindle: Applications of Electrochemistry and Nanotechnology in by Pradyumna S. Singh, Edgar D. Goluch (auth.), Noam Eliaz

By Pradyumna S. Singh, Edgar D. Goluch (auth.), Noam Eliaz (eds.)

ISBN-10: 1461421365

ISBN-13: 9781461421368

ISBN-10: 1461421373

ISBN-13: 9781461421375

The learn of electrochemical nanotechnology has emerged as researchers practice electrochemistry to nanoscience and nanotechnology. those similar volumes within the Modern facets of Electrochemistry sequence evaluation contemporary advancements and breakthroughs within the particular software of electrochemistry and nanotechnology to biology and drugs. across the world popular specialists give a contribution chapters that handle either primary and functional features of a number of key rising applied sciences in biomedicine, corresponding to the processing of recent biomaterials, biofunctionalization of surfaces, characterization of biomaterials, discovery of novel phenomena and organic tactics happening on the molecular level.

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Extra info for Applications of Electrochemistry and Nanotechnology in Biology and Medicine II

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As a rule of thumb, in the limit that Ȝ ” 10, the electron transfer step becomes the rate-limiting step in the overall voltammetric response. For the case of a spherical electrode of radius r, O = k0r / D. Thus, for a typical value of diffusion constant D = 10-5 cm2/s and an electrode of radius r = 10 nm, one can in principle measure rate constants as high as k0 = 100 cm/s. It is not surprising, therefore, that the most extensive application of nanoelectrodes has Nanoelectrochemistry 21 been to measure fast electrode kinetics of various redox species in solution.

A collage of various nanoelectrodes. (a) Scanning electron microscope (SEM) image of a 70-nm radius pulled Pt nanoelectrode. Reproduced with permission from Ref. 55, Copyright (2006) American Chemical Society. (b) Atomic force microscope (AFM) amplitude image of an exposed single SWNT nanoelectrode crossing the bottom of a pit through PMMA and SiOx layers. Reproduced with permission from Ref. 56, Copyright (2005) American Chemical Society. (c) AFM topography image of an Au nanoelectrode. Reproduced with permission from Ref.

57,70 Another bottom-up approach to making nanoelectrodes relies on depositing noble-metal nanoparticles on conducting substrates like carbon electrodes59 and single-walled carbon nanotubes (SWNTs). Nanoelectrochemistry 13 Figure 2. A collage of various nanoelectrodes. (a) Scanning electron microscope (SEM) image of a 70-nm radius pulled Pt nanoelectrode. Reproduced with permission from Ref. 55, Copyright (2006) American Chemical Society. (b) Atomic force microscope (AFM) amplitude image of an exposed single SWNT nanoelectrode crossing the bottom of a pit through PMMA and SiOx layers.

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Applications of Electrochemistry and Nanotechnology in Biology and Medicine II by Pradyumna S. Singh, Edgar D. Goluch (auth.), Noam Eliaz (eds.)


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